On formation of Al O C bonds at aluminum/polyamide joint interface
نویسندگان
چکیده
منابع مشابه
Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().
Ruthenium-catalyzed transfer hydrogenation of diverse π-unsaturated reactants in the presence of aldehydes provides products of carbonyl addition. Dehydrogenation of primary alcohols in the presence of the same π-unsaturated reactants provides identical products of carbonyl addition. In this way, carbonyl addition is achieved from the alcohol or aldehyde oxidation level in the absence of stoich...
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The presence of an Fe(O) species has been postulated as the active intermediate for the oxidation of both C−H and CC bonds in the Rieske dioxygenase family of enzymes. Understanding the reactivity of these high valent iron−oxo intermediates, especially in an aqueous medium, would provide a better understanding of these enzymatic reaction mechanisms. The formation of an Fe(O) complex at room te...
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The presence of an Fe(V)(O) species has been postulated as the active intermediate for the oxidation of both C-H and C═C bonds in the Rieske dioxygenase family of enzymes. Understanding the reactivity of these high valent iron-oxo intermediates, especially in an aqueous medium, would provide a better understanding of these enzymatic reaction mechanisms. The formation of an Fe(V)(O) complex at r...
متن کاملPhotochemistry of the α-Al₂O₃-PETN Interface.
Optical absorption measurements are combined with electronic structure calculations to explore photochemistry of an α-Al₂O₃-PETN interface formed by a nitroester (pentaerythritol tetranitrate, PETN, C₅H₈N₄O12) and a wide band gap aluminum oxide (α-Al₂O₃) substrate. The first principles modeling is used to deconstruct and interpret the α-Al₂O₃-PETN absorption spectrum that has distinct peaks att...
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ژورنال
عنوان ژورنال: Applied Surface Science
سال: 2019
ISSN: 0169-4332
DOI: 10.1016/j.apsusc.2018.10.024